For a fixed $3$-element set $e \subseteq \mathrm{Fin}\,n$, the number of $5$-element supersets of $e$ equals $\binom{n-3}{2}$, since one chooses the $2$ additional vertices from the remaining $n-3$.
Inside a $5$-element set $S$, a fixed $3$-element subset $e \subseteq S$ is contained in exactly $2$ of the $4$-element subsets of $S$ (corresponding to the $2$ elements of $S \setminus e$ one can adjoin to form a $4$-set).
Lemma 2.4.3. Any $5$-vertex tetrahedron-free $3$-uniform hypergraph has at most $7$ hyperedges. Equivalently, for every $5$-set $S$ at most $7$ hyperedges of $E$ lie inside $S$. Proved by double counting pairs (hyperedge, $4$-superset).
Improved sampling bound (Proposition 2.4.4). A tetrahedron-free $3$-uniform hypergraph on $n \geq 5$ vertices has at most $\tfrac{7}{10}\binom{n}{3}$ hyperedges; equivalently $10 |E| \leq 7 \binom{n}{3}$. The proof samples random $5$-sets and applies Lemma 2.4.3.