If $w \in W$ maps every point of chamber $C$ into chamber $D$, then $w$ in fact gives a bijection $C \leftrightarrow D$: the implication promotes to an iff. This relies on maximality of chambers as connected components of the complement of the hyperplane arrangement.
Gallery connectivity: any two chambers $C, D$ are connected by a gallery, i.e. a list of reflections through walls such that the composition sends $D$ to $C$. Proved by induction on the number of separating hyperplanes.
Any involution $s$ that fixes a hyperplane $\eta$ from the arrangement is the reflection in $\eta$ and hence is in $W$.
Transitivity of $W$ on alcoves: for any two alcoves $C, D$ there exists $w \in W$ mapping $D$ bijectively onto $C$. Built by composing a gallery of wall reflections from gallery connectivity.